Redox Reactions and Volumetric AnalysishardNUMERICAL

Out of the following five elements, how many undergo disproportionation when reacted with an alkalinRedox Reactions and Volumetric Analysis Chemistry Question

Question

Out of the following five elements, how many undergo disproportionation when reacted with an alkaline medium? $Cl_2$, $P_4$, $S_8$, $I_2$, $F_2$

Answer: 4

💡 Solution & Explanation

Chlorine, Phosphorus, Sulphur, and Iodine all disproportionate in base (e.g. $P_4 \rightarrow PH_3 + H_2PO_2^-$). Fluorine ($F_2$) is the sole exception. Being the most electronegative element, it only undergoes reduction to form $F^-$, while oxygen is forced to oxidize (forming $OF_2$ or $O_2$). Therefore, 4 elements disproportionate.

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