Qualitative and Quantitative AnalysishardNUMERICAL

To detect the presence of phosphorus in an organic compound, the compound is fused with sodium peroxQualitative and Quantitative Analysis Chemistry Question

Question

To detect the presence of phosphorus in an organic compound, the compound is fused with sodium peroxide, extracted, boiled with nitric acid, and finally treated with ammonium molybdate. This yields a canary yellow precipitate of ammonium phosphomolybdate. If the formula is $(NH_4)_3PO_4 \cdot x MoO_3$, what is the exact integer value of $x$?

Answer: 12

💡 Solution & Explanation

The canary yellow precipitate is ammonium phosphomolybdate. Its stoichiometric formula is $(NH_4)_3PO_4 \cdot 12MoO_3$. Therefore, exactly 12 equivalents of molybdenum trioxide are complexed per phosphate unit.

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