Qualitative and Quantitative AnalysishardMCQ SINGLE

Two organic compounds, I and II, are being eluted by column chromatography. It is observed that the Qualitative and Quantitative Analysis Chemistry Question

Question

Two organic compounds, I and II, are being eluted by column chromatography. It is observed that the adsorption of compound I is greater than the adsorption of compound II on the stationary phase. Which of the following is a mathematically and physically correct statement regarding their elution?

Answer: A

💡 Solution & Explanation

Since the adsorption of I is stronger than II, compound I is more firmly attached to the stationary phase and will move slowly. Compound II is less strongly attached, hence it moves faster with the mobile phase and travels a larger distance. Consequently, compound II will have a higher $R_f$ (Retardation factor) value than I.

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