Consider the transition elements of the , , and series. Which of the following statements are CORREC — Periodic Table and Periodicity Chemistry Question
Question
Consider the transition elements of the $3d$, $4d$, and $5d$ series. Which of the following statements are CORRECT regarding their ionization enthalpies?
Answer: A,B,D
💡 Solution & Explanation
The $5d$ elements have a higher $Z_{eff}$ because of the extremely poor shielding provided by the deeply buried $4f$ electrons, making their outer electrons tightly held and raising their IE over the $3d/4d$ series. $Pt$ ($5d$) > $Pd$ ($4d$). Statement C is incorrect because transition metals do not smoothly decrease in IE down a group; $5d$ is typically higher than both $3d$ and $4d$.
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