Isomerism and StereochemistryhardNUMERICAL

Determine the exact total number of geometrical isomers possible for the linear, unsymmetrical dieneIsomerism and Stereochemistry Chemistry Question

Question

Determine the exact total number of geometrical isomers possible for the linear, unsymmetrical diene represented by the condensed formula: $CH_3-CH=CH-CH=CH-Cl$.

Answer: 4

💡 Solution & Explanation

The molecule contains $n=2$ consecutive stereogenic double bonds capable of exhibiting restricted rotation (Geometrical Isomerism). Because the two terminal groups ($-CH_3$ and $-Cl$) are different, the molecule lacks overall symmetry. For unsymmetrical systems, the total number of isomers is exactly $2^n$. Thus, $2^2 = 4$ geometrical isomers are possible.

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