Isomerism and StereochemistryhardMCQ SINGLE

An unknown organic hydrocarbon, identified strictly as an alkane, exhibits clear optical activity. WIsomerism and Stereochemistry Chemistry Question

Question

An unknown organic hydrocarbon, identified strictly as an alkane, exhibits clear optical activity. What is the absolute minimum number of carbon atoms this alkane must structurally possess?

Answer: C

💡 Solution & Explanation

For an acyclic alkane to be chiral, it must contain a chiral stereocenter. The smallest possible groups to attach to a central chiral $sp^3$ carbon without duplicating any are Hydrogen (0 carbons), Methyl (1 carbon), Ethyl (2 carbons), and Propyl (3 carbons). Adding the central chiral carbon itself gives a minimum total of $0 + 1 + 2 + 3 + 1 = 7$ carbon atoms (e.g., 3-methylhexane).

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