Isomerism and StereochemistryhardMCQ MULTIPLE

Which of the following complex molecules possess the necessary restricted rotation and substituent aIsomerism and Stereochemistry Chemistry Question

Question

Which of the following complex molecules possess the necessary restricted rotation and substituent asymmetry to definitively exhibit Geometrical Isomerism?

Answer: A,B

💡 Solution & Explanation

1-Chloro-1-propene ($Cl-CH=CH-CH_3$) has different groups (Cl/H and H/Me) on both $sp^2$ carbons. Acetophenone oxime ($Ph-C(CH_3)=N-OH$) features a $C=N$ bond where the carbon is attached to a Phenyl and Methyl (different), and the nitrogen has an $-OH$ and a lone pair (different), showing GI. 1,1-Diphenyl-1-propene and Acetone oxime both have identical groups on one terminal end.

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