Properly substituted even-cumulenes (like ) cannot show Geometrical Isomerism. Nevertheless, they ho — Isomerism and Stereochemistry Chemistry Question
Question
Properly substituted even-cumulenes (like $abC=C=Cab$) cannot show Geometrical Isomerism. Nevertheless, they hold immense significance in advanced stereochemistry because they frequently exhibit:
Answer: C
💡 Solution & Explanation
Because the terminal groups in a substituted even-cumulene are firmly locked in mutually perpendicular planes, the overall molecule utterly lacks both a Plane of Symmetry (POS) and a Center of Symmetry (COS). Therefore, despite the complete absence of typical chiral $sp^3$ carbons, the entire molecular axis is chiral, and the compound exists as non-superimposable optically active enantiomers.
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