For the hydrolysis of a salt derived from a weak acid and a weak base (WA-WB), which of the followin — Ionic Equilibrium Chemistry Question
Question
For the hydrolysis of a salt derived from a weak acid and a weak base (WA-WB), which of the following mathematical expressions correctly define the system parameters? (Assuming degree of hydrolysis $h \ll 1$)
Answer: A,B,C
💡 Solution & Explanation
For a WA-WB salt, both cation and anion hydrolyze. The hydrolysis constant is $K_h = K_w / (K_a K_b)$. The degree of hydrolysis is $h = \sqrt{K_h} / (1+\sqrt{K_h}) \approx \sqrt{K_h}$, which is independent of concentration $C$ (making D incorrect). The pH relies on the difference between acid and base strengths: $pH = 7 + \frac{1}{2}pK_a - \frac{1}{2}pK_b$.
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