In the precipitation of soap (like sodium stearate, ) from its saturated aqueous solution, which com β Ionic Equilibrium Chemistry Question
Question
In the precipitation of soap (like sodium stearate, $C_{17}H_{35}COONa$) from its saturated aqueous solution, which compound is typically added to drive the equilibrium backward via the common ion effect?
Answer: B
π‘ Solution & Explanation
Soap dissolves according to the equilibrium $C_{17}H_{35}COONa_{(s)} \rightleftharpoons C_{17}H_{35}COO^-_{(aq)} + Na^+_{(aq)}$. Adding a strong electrolyte like $NaCl$ drastically increases the $[Na^+]$ concentration. Because of the common ion effect, the ionic product exceeds the $K_{sp}$ of the soap, shifting the equilibrium backward and causing the soap to precipitate out (salting out).
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