Among the three distinct position isomers of dimethylbenzene (xylene), which isomer is expected to e — Hydrocarbons Chemistry Question
Question
Among the three distinct position isomers of dimethylbenzene (xylene), which isomer is expected to exhibit the highest melting point and why?
Answer: C
💡 Solution & Explanation
The melting point of isomeric arenes depends heavily on symmetry, which dictates how closely molecules can pack in the solid state lattice. $p$ -xylene (1,4-dimethylbenzene) is the most symmetrical isomer, leading to stronger intermolecular lattice forces and the highest melting point among the xylenes.
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