HydrocarbonshardMCQ MULTIPLE

Consider the stereochemistry of addition reactions to alkynes and alkenes. Which of the following stHydrocarbons Chemistry Question

Question

Consider the stereochemistry of addition reactions to alkynes and alkenes. Which of the following statements are chemically CORRECT?

Answer: A,B,D

💡 Solution & Explanation

(A) and (B) are the classic complementary stereoselective reductions for alkynes. (D) Halogenation involves a bridged halonium ion, forcing the incoming nucleophile to attack from the opposite face (anti-addition). (C) is incorrect; reaction with cold dilute $KMnO_4$ or $OsO_4$ proceeds via a cyclic intermediate, resulting in strictly syn-hydroxylation (forming a *cis*-diol).

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