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Which of the following unsaturated hydrocarbons possesses a non-zero net molecular dipole moment?Hydrocarbons Chemistry Question

Question

Which of the following unsaturated hydrocarbons possesses a non-zero net molecular dipole moment?

Answer: D

💡 Solution & Explanation

Symmetrical trans-alkenes (like trans-hex-3-ene) and completely symmetrical alkanes (like 2,2-dimethylpropane) have their individual bond dipole moments perfectly cancel out, resulting in a net zero dipole moment. However, trans-pent-2-ene is unsymmetrical ($CH_3$ on one side, $C_2H_5$ on the other), so the dipoles do not fully cancel. cis-isomers (like cis-hex-3-ene) have bond dipoles that add up asymmetrically, creating a net dipole moment.

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