GOC and Organic Chemistry BasicshardMCQ MULTIPLE

Which of the following hydrocarbon molecules are capable of exhibiting hyperconjugation ( or overlapGOC and Organic Chemistry Basics Chemistry Question

Question

Which of the following hydrocarbon molecules are capable of exhibiting hyperconjugation ($\sigma-\pi^*$ or $\sigma-p$ overlap) in their ground state or as a reactive intermediate?

Answer: A,B,C

💡 Solution & Explanation

Propene has 3 $\alpha$ -H next to a $C=C$ bond. Toluene has 3 $\alpha$ -H next to the aromatic $\pi$ system. Ethyl carbocation has 3 $\alpha$ -H next to an empty p-orbital. Benzaldehyde has no $sp^3$ hybridized carbon with $\alpha$ -hydrogens attached to the ring, so it cannot show hyperconjugation.

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