GOC and Organic Chemistry BasicshardMCQ SINGLE

Which of the following series represents the correct decreasing order of the negative inductive () eGOC and Organic Chemistry Basics Chemistry Question

Question

Which of the following series represents the correct decreasing order of the negative inductive ($-I$) effect exerted by the functional groups?

Answer: A

💡 Solution & Explanation

The correct decreasing order of electron-withdrawing tendency ($-I$ effect) is $-NO_2 > -CN > -SO_3H > -COOH > -F > -Cl > -Br > -I > -OR > -OH > -NH_2$. Therefore, $-NO_2$ exerts a stronger pull than $-CN$, which is stronger than halogens and oxygen/nitrogen containing groups.

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