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How many of the following explicitly listed pairs of elements have nearly identical atomic radii strd and f Block Elements Chemistry Question

Question

How many of the following explicitly listed pairs of elements have nearly identical atomic radii strictly as a consequence of the Lanthanoid contraction? $(Zr, Hf)$, $(Nb, Ta)$, $(Mo, W)$, $(Y, La)$, $(Ti, Zr)$

Answer: 3

💡 Solution & Explanation

Lanthanoid contraction heavily affects the elements of the $5d$ series immediately following the Lanthanides (from $Hf$ onwards). It causes the radii of $5d$ elements to shrink to the size of their $4d$ counterparts. The affected pairs here are $(Zr, Hf)$, $(Nb, Ta)$, and $(Mo, W)$. $(Y, La)$ are not affected because $La$ comes before the $4f$ filling. $(Ti, Zr)$ represents a $3d$ - $4d$ pair, where size naturally increases. Therefore, there are exactly $3$ such pairs.

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