Coordination CompoundshardNUMERICAL

Let be the number of unpaired electrons in and be the coordination number of the central metal in . Coordination Compounds Chemistry Question

Question

Let $x$ be the number of unpaired electrons in $[MnCl_4]^{2-}$ and $y$ be the coordination number of the central metal in $[HgI_3]^-$. Find the value of $(x \times y)$.

Answer: 15

💡 Solution & Explanation

In $[MnCl_4]^{2-}$, $Mn$ is in the $+2$ oxidation state with a $3d^5$ configuration. $Cl^-$ is a weak field ligand, and the complex is tetrahedral ($sp^3$ hybridized). Thus, pairing does not occur, leaving $5$ unpaired electrons ($x = 5$). In $[HgI_3]^-$, the formula explicitly shows $3$ iodido ligands bound to mercury, giving a trigonal planar ($sp^2$) geometry with a coordination number of $3$ ($y = 3$). The product $(5 \times 3) = 15$.

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