Coordination CompoundsmediumMCQ SINGLE

What is the calculated Effective Atomic Number (EAN) of the vanadium atom in the stable hexacarbonylCoordination Compounds Chemistry Question

Question

What is the calculated Effective Atomic Number (EAN) of the vanadium atom in the stable hexacarbonylvanadate(-I) anion, $[V(CO)_6]^-$? (Atomic number V = 23)

Answer: C

💡 Solution & Explanation

The complex is $[V(CO)_6]^-$. The oxidation state of Vanadium is $-1$. Atomic number of $V = 23$. Formula: $EAN = Z - \text{O.S.} + 2(\text{C.N.})$ $EAN = 23 - (-1) + 2(6) = 23 + 1 + 12 = 36$. The anion achieves the noble gas configuration of Krypton (36).

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