In the context of organometallic chemistry and EAN calculations, how many electrons does a fully coo — Coordination Compounds Chemistry Question
Question
In the context of organometallic chemistry and EAN calculations, how many electrons does a fully coordinated cyclopentadienyl anion ($\eta^5-C_5H_5^-$) donate to the central metal atom?
Answer: D
💡 Solution & Explanation
A cyclopentadienyl anion ($C_5H_5^-$) contains an aromatic 6- $\pi$ electron system. When it binds to a metal atom in an $\eta^5$ fashion (binding through all five carbon atoms simultaneously), it donates all 6 of its $\pi$ -electrons to the metal. Therefore, it is treated as a 6-electron donor in EAN formalisms.
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