Chemical KineticshardMCQ SINGLE

The rate of a chemical reaction is observed to exactly double for a temperature rise strictly from tChemical Kinetics Chemistry Question

Question

The rate of a chemical reaction is observed to exactly double for a $10^\circ \text{C}$ temperature rise strictly from $298 \text{ K}$ to $308 \text{ K}$. Which of the following mathematical expressions correctly evaluates the activation energy ($E_a$) of this reaction?

Answer: D

💡 Solution & Explanation

The dual-temperature Arrhenius equation states $\ln \frac{k_2}{k_1} = \frac{E_a}{R} \left( \frac{T_2 - T_1}{T_1 T_2} \right)$. Here, $\frac{k_2}{k_1} = 2$, $T_1 = 298$, $T_2 = 308$, and $\Delta T = 10$. $\ln 2 = \frac{E_a \times 10}{R \times 298 \times 308} \Rightarrow E_a = \frac{R \times 298 \times 308 \times \ln 2}{10}$. Since $\ln 2 = 2.303 \log 2 \approx 0.693$, expressions A, B, and C are all algebraically identical derivations.

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