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Which of the following carbohydrates act as reducing sugars in alkaline medium?Biomolecules Chemistry Question

Question

Which of the following carbohydrates act as reducing sugars in alkaline medium?

Answer: B,C,D

💡 Solution & Explanation

Sugars with a free hemiacetal or hemiketal group can open into an aldehyde/ketone and reduce Tollens' or Fehling's reagents. Fructose, despite being a ketose, isomerizes to an aldose in base. Sucrose has an acetal linkage blocking both anomeric carbons and is non-reducing.

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