What is the ratio of the difference in energy between the first and second Bohr orbit to the differe — Atomic Structure Chemistry Question
Question
What is the ratio of the difference in energy between the first and second Bohr orbit to the difference in energy between the second and third Bohr orbit in a hydrogen atom?
💡 Solution & Explanation
The energy difference between orbits $n_1$ and $n_2$ is proportional to $(\frac{1}{n_1^2} - \frac{1}{n_2^2})$. Between $1^{st}$ and $2^{nd}$ orbits: $\Delta E_{1,2} \propto (\frac{1}{1^2} - \frac{1}{2^2}) = \frac{3}{4}$. Between $2^{nd}$ and $3^{rd}$ orbits: $\Delta E_{2,3} \propto (\frac{1}{2^2} - \frac{1}{3^2}) = \frac{1}{4} - \frac{1}{9} = \frac{5}{36}$. Ratio $= \frac{3/4}{5/36} = \frac{3}{4} \times \frac{36}{5} = \frac{27}{5}$.