Aromatic HydrocarbonsmediumNUMERICAL

How many electrons does the heteroatom (Nitrogen) exclusively contribute to the continuous, delocaliAromatic Hydrocarbons Chemistry Question

Question

How many electrons does the heteroatom (Nitrogen) exclusively contribute to the continuous, delocalized $\pi$ -electron system of the aromatic ring in a molecule of pyridine?

Answer: 1

💡 Solution & Explanation

In pyridine, the nitrogen atom is $sp^2$ hybridized. It uses two $sp^2$ orbitals for $\sigma$ bonds to adjacent carbon atoms, and the third $sp^2$ orbital holds its lone pair (which lies perfectly in the plane of the ring, orthogonal to the $\pi$ -system). Therefore, only the single unhybridized $p$ -orbital of nitrogen contributes exactly 1 electron to the aromatic $6\pi$ electron system.

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