Which of the following named reactions is specifically utilized to prepare phenyl isothiocyanate (al — Aromatic Hydrocarbons Chemistry Question
Question
Which of the following named reactions is specifically utilized to prepare phenyl isothiocyanate (also known as mustard oil due to its pungent smell) from aniline?
Answer: B
💡 Solution & Explanation
In the Hoffmann Mustard Oil reaction, a primary amine like aniline is warmed with carbon disulfide ($CS_2$) and mercuric chloride ($HgCl_2$) to form phenyl isothiocyanate ($C_6H_5-N=C=S$). The Carbylamine reaction produces isocyanide; Schotten-Baumann is for benzoylation; and the Sandmeyer reaction converts diazonium salts to aryl halides/cyanides.
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