Aromatic HydrocarbonshardNUMERICAL

How many distinct, major Kekule-style resonance structures (canonical forms) can be drawn to represeAromatic Hydrocarbons Chemistry Question

Question

How many distinct, major Kekule-style resonance structures (canonical forms) can be drawn to represent the delocalization of the positive charge in the arenium ion formed by the electrophilic attack on an unsubstituted benzene ring?

Answer: 3

💡 Solution & Explanation

For unsubstituted benzene, attack by an electrophile leaves a conjugated system of 5 carbon atoms. The positive charge is localized primarily on the ortho and para positions relative to the $sp^3$ carbon, generating exactly 3 stable resonance structures.

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