An aromatic compound 'A' on heating with aqueous ammonia forms compound 'B'. Compound 'B' on heating — Amines Chemistry Question

💡 Solution & Explanation

Compound 'C' is aniline ($C_6H_5NH_2$). It is produced from 'B' via the Hofmann bromamide degradation using $Br_2/KOH$. This dictates that 'B' must be benzamide ($C_6H_5CONH_2$). Benzamide is synthesized by reacting benzoic acid ('A', $C_6H_5COOH$) with ammonia to form ammonium benzoate, followed by thermal dehydration.