Aldehydes Ketones and Carboxylic AcidshardNUMERICAL

Evaluate the following synthetic procedures: 1. Reaction of Dialkyl cadmium with Acyl chloride. 2. RAldehydes Ketones and Carboxylic Acids Chemistry Question

Question

Evaluate the following synthetic procedures: 1. Reaction of Dialkyl cadmium with Acyl chloride. 2. Rosenmund reduction. 3. Stephen's reaction. 4. Kucherov's hydration of ethyne ($HC\equiv CH$). 5. Wacker process on propene. How many of these 5 specific processes are designed to yield a ketone as the major organic product?

Answer: 2

💡 Solution & Explanation

1. Dialkyl cadmium + acyl chloride $\rightarrow$ Ketone. 2. Rosenmund $\rightarrow$ Aldehyde. 3. Stephen's $\rightarrow$ Aldehyde. 4. Hydration of ethyne $\rightarrow$ Acetaldehyde (an aldehyde). 5. Wacker process on propene (or any alkene other than ethene) $\rightarrow$ Ketone (Acetone). Thus, exactly 2 processes yield ketones.

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