Aldehydes Ketones and Carboxylic AcidshardMCQ SINGLE

In the industrial Wacker process for the synthesis of acetaldehyde, ethene gas is treated with an aqAldehydes Ketones and Carboxylic Acids Chemistry Question

Question

In the industrial Wacker process for the synthesis of acetaldehyde, ethene gas is treated with an aqueous solution of $PdCl_2$. What is the specific chemical function of $CuCl_2$ and air ($O_2$) in this catalytic system?

Answer: B

💡 Solution & Explanation

During the Wacker process, $Pd(II)$ oxidizes ethene to acetaldehyde and is itself reduced to elemental Palladium metal, $Pd(0)$. To make the process catalytic and continuous, $CuCl_2$ oxidizes $Pd(0)$ back to $Pd(II)$. The reduced Copper(I) chloride ($CuCl$) is then re-oxidized to $CuCl_2$ by atmospheric oxygen.

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