Alcohols Phenols and EthershardMCQ SINGLE

The acid-catalyzed dehydration of ethanol can yield either an alkene or an ether depending on the reAlcohols Phenols and Ethers Chemistry Question

Question

The acid-catalyzed dehydration of ethanol can yield either an alkene or an ether depending on the reaction conditions. What are the specific optimum temperature and the dominant mechanism required to maximize the yield of diethyl ether?

Answer: B

💡 Solution & Explanation

The dehydration of primary alcohols to form ethers is a nucleophilic bimolecular ($S_N2$) substitution where one alcohol molecule attacks another protonated alcohol molecule. This process is favored at a lower temperature of $413 \text{ K}$. At higher temperatures (e.g., $443 \text{ K}$), intramolecular elimination ($E2$) dominates, yielding ethene.

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