Alcohols can be prepared from alkenes using several distinct methods. Which of the following methods β Alcohols Phenols and Ethers Chemistry Question
Question
Alcohols can be prepared from alkenes using several distinct methods. Which of the following methods proceed explicitly via a classical carbocation intermediate and are therefore prone to structural rearrangements?
Answer: A,D
π‘ Solution & Explanation
Acid-catalyzed hydration (with dilute $H_2SO_4$) and standard hydrohalogenation (with $HCl$) both involve classical carbocation intermediates, which can rearrange to form more stable tertiary structures. Hydroboration and oxymercuration specifically avoid free classical carbocations to prevent rearrangements.
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