Haloalkanes and HaloareneshardMCQ SINGLE

What is the correct reactivity order towards for para-substituted halonitrobenzenes ()?Haloalkanes and Haloarenes Chemistry Question

Question

What is the correct reactivity order towards $S_NAr$ for para-substituted halonitrobenzenes ($p-XC_6H_4NO_2$)?

Answer: A

💡 Solution & Explanation

In the $S_NAr$ addition-elimination mechanism, the initial attack of the nucleophile is the rate-determining step. Fluorine is the most electronegative, creating the largest partial positive charge on the target carbon, which leads to the fastest nucleophilic addition.

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