When a highly dilute aqueous solution of silver nitrate () is cautiously added dropwise to a slight — Surface Chemistry Chemistry Question
Question
When a highly dilute aqueous solution of silver nitrate ($AgNO_3$) is cautiously added dropwise to a slight volumetric excess of dilute potassium iodide ($KI$) solution, a highly stable lyophobic colloidal sol of $AgI$ is formed. What is the specific electrical nature of this resulting sol and its fundamental origin?
💡 Solution & Explanation
When $AgNO_3$ is added to an excess of $KI$, the resulting precipitate of $AgI$ is formed in an environment where the common ion $I^-$ is in large excess. According to the preferential adsorption theory of the electrical double layer, the precipitate strictly adsorbs the common ion from the medium, forming a negatively charged sol ($AgI/I^-$).