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Which of the following statements accurately compare the thermal stability of compounds containing ps Block Elements Chemistry Question

Question

Which of the following statements accurately compare the thermal stability of compounds containing polyatomic anions across the s-block?

Answer: A,B

💡 Solution & Explanation

Thermal stability of large polyatomic anions (carbonates, sulphates) increases down the group as the size of the cation increases (decreasing polarizing power). $BeCO_3$ is so unstable it decomposes easily to $BeO$ and $CO_2$, so it is kept in a $CO_2$ atmosphere. Hydroxide stability and basicity *increase* down the group. Group 1 sulphates are highly stable to heat and generally do not decompose, they merely melt.

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