In the estimation of carbon and hydrogen by Liebig's method, if the organic compound also contains n — Practical Organic Chemistry and Purification Chemistry Question
Question
In the estimation of carbon and hydrogen by Liebig's method, if the organic compound also contains nitrogen, halogens, and sulphur, what modifications are required in the combustion tube?
Answer: A
💡 Solution & Explanation
When interfering elements are present in Liebig's test, their oxides would artificially inflate the $CO_2$ and $H_2O$ measurements. A copper gauze reduces nitrogen oxides to $N_2$ (which is not absorbed). Silver gauze traps halogens as $AgX$, and fused lead chromate traps sulphur oxides as $PbSO_4$.
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