During the vulcanization of natural rubber with sulphur, what specific sites on the polyisoprene cha — Polymers Chemistry Question
Question
During the vulcanization of natural rubber with sulphur, what specific sites on the polyisoprene chains are primarily attacked to form the intermolecular $-S-S-$ cross-links?
Answer: C
💡 Solution & Explanation
Vulcanization involves heating rubber with sulphur. The sulphur forms cross-links (bridges) between separate polymer chains specifically at the highly reactive allylic carbon positions (next to the double bond) or directly across the double bonds themselves.
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