Bakelite is manufactured by extensively heating the linear prepolymer Novolac with an excess of form — Polymers Chemistry Question
Question
Bakelite is manufactured by extensively heating the linear prepolymer Novolac with an excess of formaldehyde. What is the primary macroscopic and structural change that converts Novolac into Bakelite?
Answer: C
💡 Solution & Explanation
Heating Novolac with formaldehyde causes further electrophilic aromatic substitution, creating extensive methylene ($-CH_2-$) cross-links between separate linear chains at available ortho and para sites. This yields Bakelite, a rigid, infusible, thermosetting 3D network polymer.
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