PolymershardMCQ SINGLE

Which of the following vinyl monomers is most susceptible to anionic polymerization initiated by strPolymers Chemistry Question

Question

Which of the following vinyl monomers is most susceptible to anionic polymerization initiated by strong bases such as $n$ -butyllithium or $KNH_2$?

Answer: C

💡 Solution & Explanation

Anionic polymerization is highly selective and favorable for monomers containing strong electron-withdrawing groups, which stabilize the intermediate carbanion. The cyano group ($-CN$) in acrylonitrile is strongly electron-withdrawing, making it highly susceptible to anionic initiation.

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