Which of the following vinyl monomers is most susceptible to anionic polymerization initiated by str — Polymers Chemistry Question
Question
Which of the following vinyl monomers is most susceptible to anionic polymerization initiated by strong bases such as $n$ -butyllithium or $KNH_2$?
Answer: C
💡 Solution & Explanation
Anionic polymerization is highly selective and favorable for monomers containing strong electron-withdrawing groups, which stabilize the intermediate carbanion. The cyano group ($-CN$) in acrylonitrile is strongly electron-withdrawing, making it highly susceptible to anionic initiation.
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