Periodic Table and PeriodicityhardMCQ SINGLE

According to the Mulliken scale of electronegativity, if the first ionization energy () and the elecPeriodic Table and Periodicity Chemistry Question

Question

According to the Mulliken scale of electronegativity, if the first ionization energy ($IE_1$) and the electron affinity ($EA$) of a hypothetical element are experimentally found to be $13.0 \text{ eV/atom}$ and $3.8 \text{ eV/atom}$ respectively, what is its approximate electronegativity on the Pauling scale?

Answer: B

💡 Solution & Explanation

On the Mulliken scale, electronegativity is the arithmetic mean of IP and EA in eV/atom: $EN_M = \frac{13.0 + 3.8}{2} = 8.4$. The relationship between the Pauling scale ($X_P$) and the Mulliken scale ($X_M$) is given by $X_P = \frac{X_M}{2.8}$. Therefore, Pauling EN $= \frac{8.4}{2.8} = 3.0$.

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