Periodic Table and PeriodicityhardNUMERICAL

Consider the following specific elements from the 2nd and 3rd periods: and . Based on periodic trendPeriodic Table and Periodicity Chemistry Question

Question

Consider the following specific elements from the 2nd and 3rd periods: $Li, B, C, N, O, Na,$ and $Mg$. Based on periodic trends and orbital penetration anomalies, exactly how many of these elements possess a first ionization enthalpy strictly LESS than that of Beryllium ($Be$)?

Answer: 4

💡 Solution & Explanation

Beryllium has a stable fully-filled $2s^2$ configuration. Comparing values: $Li < Be$. Due to penetration effect, $B < Be$. Going down the group, $Mg < Be$. $Na$ is an alkali metal below $Li$, so $Na < Li < Be$. Elements to the right ($C, N, O$) have higher $Z_{eff}$ and thus higher IE than $Be$. The elements with lower $IE_1$ than $Be$ are $Li, B, Na,$ and $Mg$. Total = 4.

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full IChO (Chemistry Olympiad) content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry