The formation of the oxide ion, , from a gaseous oxygen atom requires first an exothermic and then a — Periodic Table and Periodicity Chemistry Question
Question
The formation of the oxide ion, $O^{2-}_{(g)}$, from a gaseous oxygen atom requires first an exothermic and then an endothermic step. The second electron gain enthalpy is positive primarily because:
Answer: C
💡 Solution & Explanation
The first electron addition is exothermic ($O + e^- \rightarrow O^-; \Delta H = -141 \text{ kJ/mol}$). Adding a second electron means forcing a negative electron onto an already negatively charged ion ($O^-$). The strong inter-electronic Coulombic repulsion overwhelmingly outweighs the nuclear attraction, making the process highly endothermic ($+744 \text{ kJ/mol}$).
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