Periodic Table and PeriodicityhardMCQ SINGLE

Why is the second ionization enthalpy () of Oxygen strictly greater than the second ionization enthaPeriodic Table and Periodicity Chemistry Question

Question

Why is the second ionization enthalpy ($IE_2$) of Oxygen strictly greater than the second ionization enthalpy of Nitrogen?

Answer: B

💡 Solution & Explanation

The first $IE$ of N is higher than O due to N's half-filled $2p^3$ state. However, after removing one electron, the $O^+$ ion now possesses the half-filled $2p^3$ configuration, making its second electron extremely difficult to remove compared to the $N^+$ ion (which is $2p^2$). Thus, $IE_2(O) > IE_2(N)$.

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