Nuclear Chemistry and RadioactivityhardNUMERICAL

The fractional atomic weight of natural Chlorine is . This is primarily due to the existence of two Nuclear Chemistry and Radioactivity Chemistry Question

Question

The fractional atomic weight of natural Chlorine is $35.5$. This is primarily due to the existence of two stable isotopes: ${}^{35}Cl$ and ${}^{37}Cl$. If the molar abundance ratio of ${}^{35}Cl$ to ${}^{37}Cl$ in nature is $x : 1$, what is the precise numerical value of $x$?

Answer: 3

💡 Solution & Explanation

Let the fractional abundance of ${}^{37}Cl$ be $y$. Then the fractional abundance of ${}^{35}Cl$ is $(1-y)$. The average atomic weight is $35(1-y) + 37y = 35.5$. Solving this yields $35 - 35y + 37y = 35.5 \Rightarrow 2y = 0.5 \Rightarrow y = 0.25$. Thus, ${}^{37}Cl$ is 25% and ${}^{35}Cl$ is 75%. The ratio of ${}^{35}Cl$ to ${}^{37}Cl$ is $75 : 25$, which simplifies to $3 : 1$. Therefore, $x = 3$.

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