Mole Concept and Some Basic Concepts of ChemistryhardMCQ SINGLE

of an unknown oxide of nitrogen gives of nitrogen gas at STP. of another oxide of nitrogen gives of Mole Concept and Some Basic Concepts of Chemistry Chemistry Question

Question

$4.4\text{ g}$ of an unknown oxide of nitrogen gives $2.24\text{ L}$ of nitrogen gas at STP. $60\text{ g}$ of another oxide of nitrogen gives $22.4\text{ L}$ of nitrogen gas at STP. This analytical data perfectly illustrates which of the following laws of chemical combination?

Answer: B

💡 Solution & Explanation

In the first oxide, $2.24\text{ L}$ of $N_2$ at STP ($0.1\text{ mole}$ or $2.8\text{ g}$) combines with $4.4 - 2.8 = 1.6\text{ g}$ of Oxygen. Ratio $N:O = 2.8:1.6 = 14:8$. In the second oxide, $22.4\text{ L}$ of $N_2$ at STP ($1.0\text{ mole}$ or $28\text{ g}$) combines with $60 - 28 = 32\text{ g}$ of Oxygen. Ratio $N:O = 28:32 = 14:16$. For a fixed mass of Nitrogen ($14\text{ g}$), the ratio of combining masses of Oxygen is $8:16 = 1:2$, which is a simple whole-number ratio, proving the Law of Multiple Proportions.

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