IUPAC and NomenclaturehardNUMERICAL

A certain saturated acyclic alkane has a molecular weight of and contains a 2-methyl group. How manyIUPAC and Nomenclature Chemistry Question

Question

A certain saturated acyclic alkane has a molecular weight of $72 \text{ g/mol}$ and contains a 2-methyl group. How many primary ($1^\circ$) hydrogen atoms are in one molecule of this compound?

Answer: 9

💡 Solution & Explanation

The general formula of an alkane is $C_nH_{2n+2}$. Setting the mass: $12n + 2n + 2 = 72 \Rightarrow 14n = 70 \Rightarrow n = 5$. The alkane is a pentane isomer with a 2-methyl group, i.e., 2-methylbutane (isopentane). Its structure is $CH_3-CH(CH_3)-CH_2-CH_3$. It has three $1^\circ$ carbons, giving $3 \times 3 = 9$ primary hydrogens.

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