Which of the following specific molecular setups will definitively FAIL to exhibit macroscopic Geome — Isomerism and Stereochemistry Chemistry Question
Question
Which of the following specific molecular setups will definitively FAIL to exhibit macroscopic Geometrical Isomerism?
Answer: B,D
💡 Solution & Explanation
Setup A is a 3-bond odd cumulene, which maintains co-planar ends and shows GI. Setup C is a square planar triphenyl system, which forces all three rings into the same plane, successfully showing GI. However, Setup B is a 2-bond even cumulene (allene), ending in perpendicular planes (no GI). Setup D is a heavily hindered biphenyl forced into orthogonal perpendicular planes to relieve steric strain, rendering cis/trans measurement impossible (no GI).
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