Ionic EquilibriumhardMCQ SINGLE

For a weak electrolyte generalizing as with a " molar" initial concentration and a degree of dissociIonic Equilibrium Chemistry Question

Question

For a weak electrolyte generalizing as $A_xB_y$ with a "$c$ molar" initial concentration and a degree of dissociation $\alpha$, which of the following expressions precisely defines its equilibrium constant $K_{eq}$?

Answer: A

💡 Solution & Explanation

The dissociation reaction is $A_xB_y \rightleftharpoons xA^{y+} + yB^{x-}$. Initially, $[A_xB_y] = c$. At equilibrium, $[A_xB_y] = c(1-\alpha)$, $[A^{y+}] = xc\alpha$, and $[B^{x-}] = yc\alpha$. The equilibrium constant is $K_{eq} = \frac{[A^{y+}]^x[B^{x-}]^y}{[A_xB_y]} = \frac{(xc\alpha)^x(yc\alpha)^y}{c(1-\alpha)} = \frac{x^x y^y c^{x+y} \alpha^{x+y}}{c(1-\alpha)} = \frac{x^x y^y c^{x+y-1} \alpha^{x+y}}{1-\alpha}$.

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full IChO (Chemistry Olympiad) content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry