Ionic EquilibriumhardMCQ MULTIPLE

The total number of different kinds of buffers that can be theoretically obtained during the completIonic Equilibrium Chemistry Question

Question

The total number of different kinds of buffers that can be theoretically obtained during the complete step-wise titration of $H_3PO_4$ with $NaOH$ is three. Which of the following conjugate acid-base pairs constitute these specific buffers?

Answer: A,B,C

💡 Solution & Explanation

$H_3PO_4$ is a triprotic acid and undergoes titration in three distinct equivalence steps. The intermediate buffer regions correspond to the conjugate pairs of successive ionizations: Region 1 is $H_3PO_4 / H_2PO_4^-$. Region 2 is $H_2PO_4^- / HPO_4^{2-}$. Region 3 is $HPO_4^{2-} / PO_4^{3-}$. A pair like $H_3PO_4 / HPO_4^{2-}$ differs by two protons and does not form a standard simple buffer.

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