Ionic EquilibriumhardNUMERICAL

What will be the exact resultant pH when of an aqueous solution of () is mixed with of an aqueous soIonic Equilibrium Chemistry Question

Question

What will be the exact resultant pH when $150 \text{ mL}$ of an aqueous solution of $HCl$ ($pH = 2.0$) is mixed with $350 \text{ mL}$ of an aqueous solution of $NaOH$ ($pH = 12.0$)?

Answer: 11.6

💡 Solution & Explanation

For $HCl$ at $pH=2$, $[H^+] = 10^{-2} \text{ M}$. Moles of $H^+ = 150 \times 10^{-2} = 1.5 \text{ mmol}$. For $NaOH$ at $pH=12$, $pOH = 2$, so $[OH^-] = 10^{-2} \text{ M}$. Moles of $OH^- = 350 \times 10^{-2} = 3.5 \text{ mmol}$. Upon mixing, $H^+$ and $OH^-$ neutralize. Remaining $OH^- = 3.5 - 1.5 = 2.0 \text{ mmol}$. Total volume is $150 + 350 = 500 \text{ mL}$. Final $[OH^-] = 2.0 / 500 = 4 \times 10^{-3} \text{ M}$. $pOH = -\log(4 \times 10^{-3}) = 3 - \log 4 = 3 - 0.602 = 2.4$. The resulting $pH = 14 - 2.4 = 11.6$.

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