Old lead paintings often turn dark or black over time due to the atmospheric forming lead sulphide ( — Hydrogen Chemistry Question
Question
Old lead paintings often turn dark or black over time due to the atmospheric $H_2S$ forming lead sulphide ($PbS$). The original white colour of the painting can be meticulously restored using a dilute solution of $H_2O_2$. What is the exact chemical role of $H_2O_2$ in this restoration process?
💡 Solution & Explanation
Blackened statues and paintings are coated with $PbS$ (lead sulphide). $H_2O_2$ acts as a strong oxidizing agent, oxidizing the black $PbS$ to white $PbSO_4$ (lead sulphate), thereby safely restoring the painting's original white colour without destroying the underlying pigment. The reaction is: $PbS(s) + 4H_2O_2(aq) \rightarrow PbSO_4(s) + 4H_2O(l)$.