GOC and Organic Chemistry BasicshardMCQ MULTIPLE

Assuming reactions are strictly in the gaseous phase (ignoring solvation), which of the following orGOC and Organic Chemistry Basics Chemistry Question

Question

Assuming reactions are strictly in the gaseous phase (ignoring solvation), which of the following orders of basic strength are correct purely due to inductive effects?

Answer: A,B,C

💡 Solution & Explanation

In the gas phase, basicity correlates with the $+I$ effect. Ethyl has a stronger $+I$ effect than methyl (Option A). Dimethylamine has two $+I$ groups vs one in methylamine (Option B). In $NF_3$, highly electronegative fluorine exerts a strong $-I$ effect, deeply pulling electron density away from nitrogen, making $NH_3$ much more basic (Option C).

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